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Marmite by product could help recycle metal waste

As the world becomes increasingly dependent on electronics, the hunt is on for ways of effectively recycling them. But electronics often contain many different metals, which are difficult to separate for effective recycling. Scientists have now discovered that spent brewer’s yeast, a byproduct of beer manufacturing which is also the basis for Marmite, can be used multiple times to retrieve metals like aluminium, zinc, and copper from a solution. When the method was tested on a polymetallic waste stream, they recovered more than 50 per cent of the copper and 90 per cent of the zinc present.

When we recycle electronic devices we can no longer use, we expect to make the most out of the precious natural resources that went into building them. But electronic waste is notoriously difficult to recycle, because it’s hard to separate the different metals in the waste from each other. Scientists have now found a way of selectively capturing metals from a waste stream using spent brewer’s yeast, the same beer byproduct that goes into Marmite. Not only that: the yeast can be reused, making the process even more eco-friendly.

“Electronic waste is difficult to recycle because it is very heterogeneous,” said Dr Klemens Kremser of the University of Natural Resources and Life Sciences, Vienna, corresponding author of the article in Frontiers in Bioengineering and Biotechnology. “Getting the metals in solution is a first step, but the selective recovery of the metals remains a challenge. Compared to processes such as chemical precipitation, biosorption using spent brewer’s yeast presents a cheap and environmentally friendly approach.”

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Several options already exist for separating out the different component metals of electronic waste, including other biosorbents — biological materials which can be used to soak up pollution. However, they all have significant downsides. For instance, chemical precipitation produces contaminated slag, while biochar — a biosorbent which is similar to charcoal — is difficult to separate from wastewater.

So the scientists turned to brewer’s yeast. Because leftover brewer’s yeast is a common byproduct of beer-brewing, it’s cheap and widely available. This research was supported by COMET (Competence Center for Excellent Technologies), the Austrian program for competence centers.

The scientists acquired 20 liters of spent brewer’s yeast, separated the biomass from leftover brewing residues, and dried out the biomass. Electrostatic interactions on the surface of the yeast allow metal ions to stick to that surface — a process called adsorption. Changing the pH of this solution alters the interactions, which can allow the yeast to adsorb more or different metal ions, depending on the contents of the solution and the specific pH.

The scientists chose to test the yeast biomass against zinc, aluminium, copper, and nickel, economically important metals. The scientists tested each metal solution at a range of different pHs and temperatures, to gauge whether it was possible to increase the strength of the interactions and recover more metal. The scientists also tested the yeast against a real polymetallic waste stream.

“Using waste biomass for metal recovery is not a completely new process, but the selectivity of biosorption processes is a key factor for efficient metal recovery from polymetallic waste streams,” said Anna Sieber, PhD fellow of K1-MET, an Austrian metallurgical research center, and first author of the article. “We demonstrated high metal recovery rates from a complex metal solution using an environmentally friendly and cheap biomass. Yeast biomass is considered a safe organism, and the demonstrated reusability of the biomass makes it an economically feasible approach.”

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The scientists were able to recover more than 50 per cent of aluminium, more than 40 per cent of copper, and more than 70 per cent of zinc from the test metal solutions. More than 50 per cent of copper and over 90 per cent of zinc were retrieved from the polymetallic waste stream they tested the yeast on.

Changing the temperature had relatively little impact on efficiency, except for zinc, where it raised the recovery rate by 7.6 per cent. Similarly, adjusting the pH had a limited effect on most of the metal solutions, except for aluminium, where it improved the efficiency of recovery by 16 per cent.

“The metals can be removed from the yeast surface by acid treatment and thus could be recycled,” said Sieber. “It would be interesting to investigate potential applications for these reclaimed metals.”

The yeast itself could also be recycled without heavily impacting its ability to recover metal: the scientists were able to use it five times to recover different metals.

However, the scientists caution that the metal recovery process needs testing with much larger studies in real-life conditions before it can be implemented on an industrial scale.

“The metal removal process in this study was optimised for the four metals in question,” said Kremser. “The concentration of potentially interfering metal ions was very low in our starting solutions, but this would be important to consider when applying this approach to different mixed metal solutions.”

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